B3 - method for determining the correct linear combination of zeroth order eigenfunctions

  1. recognise that there is a s-fold degeneracy

  2. write down the complete set of degenerate eigenfunctions |unα0⟩ with the same unperturbed energy En0 for Ds

  3. calculate the elements in the s×s matrix, Vαβ=⟨unβ0|V^|unα0⟩

⟨unβ0|V^|ϕnα0⟩=Eni1⟨unβ0|ϕni0⟩∑α=1s(⟨u|nβ0V^|ϕnα0⟩−Eni1⟨unβ0|ϕni0⟩)ciβ=0,i=1,…,s
  1. solve the characteristic determinant to find the s eigenvalues, the first-order corrections

  2. use these eigenvalues to calculate ciα