B3 - method for determining the correct linear combination of zeroth order eigenfunctions
-
recognise that there is a
-fold degeneracy -
write down the complete set of degenerate eigenfunctions
with the same unperturbed energy for -
calculate the elements in the
matrix,
- these
equations give the required values for - setting the determinant of the term in the brackets to zero gives the
roots , the first-order energy shifts
-
solve the characteristic determinant to find the
eigenvalues, the first-order corrections -
use these eigenvalues to calculate