B1 - the degeneracy problem
-
suppose
of is -fold degenerate -
there are
linearly independent orthogonal eigenfunctions belonging to this eigenvalue, with -
any linear combination of these is also an eigenfuction of
-
the second order non-degenerate perturbation theory assumed
, which does not hold for -
for zero-order states needed in the PT expansion are not uniquely defined
-
considering a 2-fold degeneracy with
, both having -
the deminators in the first-order correction to wavefunction and second-order correction to energy will be zero
-
if a perturbation
lifts the degeneracy giving , whose linear combinations will not be eigenfunctions as -
slowly removing the perturbation
, these will return to , different from the original eigenstates -
so need to find
normed states:
are constant coefficients which are the correct linear combinations for the PT