PX262 - F2a - particle in an infinite potential well
s- consider a potential well in 3D:
- using separation of variables for the wavefunction:
- substituting into the time-independent schrödinger equation:
- each term should be equal to a constant, and the three constants should add up to
- looking at the
-dependent term: - this is exactly the same as the equation for the 1D potential well, and the solution is:
where, is the quantum number labelling states - and the wavefunction is:
where, means cosine for odd and sine for even values of - the full solution is:
- the energy eigenvalues are the sums of the three contributions: