PX262 - C2a - the dynamical variables
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dynamical variables: position, momentum, energy, etc
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in classical physics, they are represented by algebraic variables:
, , , which can have all possible (continuous) values -
in quantum mechanics, only some values are allowed
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this also needs to work together with the wavefunction to obtain information
operators
- from the time independent schrödinger equation:
where,
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a mathematical operator is an object which acts on a function and produces a new function, which need not be the same function
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in the above case, the same function is obtained
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the special cases are called eigenfunctions, and the values of
are called eigenvalues:
operator
eigenfunction
eigenvalue -
eigenfunctions correspond to the single eigenvalue of the system
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if there is a system described by the eigenfunction of the given operator, and measurements of the corresponding variable is taken, the given eigenvalue is obtained
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it is reasonable to expect that if a second measurement is taken, the same answer is obtained
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if the measurement of a given value is obtained, the wavefunction immediately after the measurement should be the corresponding eigenfunction (
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the dynamical variables are represented by operators, and the eigenvalues of these operators correspond to the possible measurement outcomes
hermitian
- if
is a hermitian operator: where and are well-defined functions that vanish at infinity - the momentum operator: $$\begin{align*}
\int f \hat P_{x} g ,d\tau &= -i\hbar \int_{-\infty}^{\infty} f \frac{\partial g}{\partial x},dx \
&= -i\hbar \left( [fg]{-\infty}^{\infty}- \int{-\infty}^{\infty} g \frac{\partial f}{\partial x},dx \right) \
&= + i\hbar \int_{-\infty}^{\infty} g \frac{\partial f}{\partial x},dx \
\therefore \int f \hat P_{x} g ,d\tau &= \int_{-\infty}^{\infty} g \hat P_{x}^{} f,dx
\end{align}$$